Khoo, E.S. You can find out more in our Privacy Policy. Volume 56: D. Shaw, A. Skrzecz, J.W. [15], Ammonium sulfate becomes ferroelectric at temperatures below -49.5 °C. Which cookies and scripts are used and how they impact your visit is specified on the left. Volume 48: F. Getzen, G. Hefter and A. Maczynski. Volume 74: Jiri Hála and James D. Navratil. As a salt of a strong acid (H2SO4) and weak base (NH3), its solution is acidic; pH of 0.1 M solution is 5.5. Volume 45/46: R.P.T. The goal of the SDS from the start was to compile all experimental solubility data in the world’s reviewed chemistry literature and to critically evaluate this body of data using international teams of experts under the auspices of IUPAC. The chlorides, bromides, and iodides of all metals except lead, silver, and mercury(I) are soluble in water. IUPAC uses information collected through cookies or in other forms to improve experience on our site and pages, and analyze how it is used. Volume 70: Russell Paterson, Yuri Yampol’skii, and Peter G.T. Schneider, C. Guminski and Z. Galus. [2] Anhydrous double sulfates of ammonium also occur in the Langbeinites family. Volume 72: Valerii P. Sazonov, Kenneth N. Marsh, David G. Shaw, Mariya F. Chernysheva, Nikolai V. Sazonov, and Hideo Akaiwa. With trivalent metal ions, alums such as ferric ammonium sulfate are formed. https://doi.org/10.1134/S1070427209060123, DOI: https://doi.org/10.1134/S1070427209060123, Over 10 million scientific documents at your fingertips, Not logged in The nitrates, chlorates, and acetates of all metals are soluble in water. solubility, acidity or basicity, stability, reactivity etc. Chan, K.H. 2. Silver acetate is sparingly soluble. Bansal. Expressions of interest from qualified individuals interested in volume preparation as well as questions about the series and its use should be directed to the Editor-in-Chief, Mark Salomon . Tomkins and N.P. Chan, I.N. Ammonium sulfate forms many double salts (ammonium metal sulfates) when its solution is mixed with equimolar solutions of metal sulfates and the solution is slowly evaporated. Volume 63: H.U. 3. Volume 41: C.-Y. H2O2 in organic solvents (glycerol, ethylene glycol, TOSOL-A40 OM antifreeze), in mixtures of an organic solvent and water, and in pure water was studied. Volume 55: S. Siekierski and S.L. Ref. Double metal sulfates include ammonium cobaltous sulfate, ferrous diammonium sulfate, ammonium nickel sulfate which are known as Tutton's salts and ammonium ceric sulfate. Ammonium sulfate occurs naturally as the rare mineral mascagnite in volcanic fumaroles and due to coal fires on some dumps. Clever and C.L. Russ J Appl Chem 82, 995–999 (2009). In January 2010, these substances were also banned in Afghanistan for the same reason. Lorimer. Calcium carbonate precipitates as a solid, leaving ammonium sulfate in the solution. Methods Enzymol., 1, 67-90 (1955). Young. This site uses functional cookies and external scripts to improve your experience. Since the first volume of the SDS was published in 1979 great advances have occurred in the electronic storage and search for chemical property values including solubility. NOTE: These settings will only apply to the browser and device you are currently using. Volume 67: Ari L. Horvath and Forrest W. Getzen. The most common use is as a soil fertilizer. Clever. Ammonium sulfate is an inorganic sulfate salt obtained by reaction of sulfuric acid with two equivalents of ammonia.A high-melting (decomposes above 280℃) white solid which is very soluble in water (70.6 g/100 g water at 0℃; 103.8 g/100 g water at 100℃), it is widely used as a fertilizer for alkaline soils. 2H2O). Heating at higher temperatures results in decomposition into ammonia, nitrogen, sulfur dioxide, and water.[17]. Research Triangle Park, NC 27709-3757, USA. Volume 75: Hans Ulrich Borgstedt and Cezary Guminski, Volume 84: Jiri Hála and Hiroshi Miyamoto, Volume 87: Tomasz Mioduski, Cezary Guminski and Dewen Zeng, Volume 89: Jitka Eysseltová and Violetta Timofeevna Orlova, Volume 93: Jitka Eysseltováa and Roger Bouaziz, Volume 94: Tomasz Mioduski, Cezary Guminski and Dewen Zeng, Volume 97: Peter G. T. Fogg and Adam Skrzecz, Volume 100: Tomasz Mioduski, Cezary Gumiński, and Dewen Zeng, Volume 101: Marian Góral, David G. Shaw, Andrzej Mączyński, Barbara Wiśniewska-Gocłowska and Paweł Oracz, Volume 103: H. Lawrence Clever, Rubin Battino, Hiroshi Miyamoto, Yuri Yampolski and Colin L. Young, Volume 104: Julia Sohr, Wolfgang Voigt and Dewen Zeng. Volume 13: S. Siekierski, T. Mioduski and M. Salomon. Volume 16/17: E. Tomlinson and A. Regosch, Antibiotics: Volume 25: C. Hirayama, Z. Galus and C. Guminski. https://doi.org/10.1134/S1070427209060123, Physicochemical Studies of Systems and Processes. You may change your settings at any time. In aqueous solution the reactions are those of NH4+ and SO4−2 ions. Volume 64: H.U. The IUPAC-NIST Solubility Database provides search capability for selected systems. GCY/AJH 4/05 Sigma brand products are sold through Sigma-Aldrich, Inc. It contains 21% nitrogen and 24% sulfur. For example, most reactions are carried out in solution where a solvent needs to dissolve the reactents to allow the molecules to be in the same phase so that they can collide and react (the solvent Masson, H.D. A history of the early work on the SDS was prepared by Professor Larry Clever, one of the original participants (Chem Int 2004, 24(3), p. 12; doi:10.1515/ci.2004.26.3.12). [19], InChI=1S/2H3N.H2O4S/c;;1-5(2,3)4/h2*1H3;(H2,1,2,3,4), InChI=1/2H3N.H2O4S/c;;1-5(2,3)4/h2*1H3;(H2,1,2,3,4), Except where otherwise noted, data are given for materials in their, ASTM Standard Specification for Rubber Concentrates D 1076-06, "Protein Precipitation Using Ammonium Sulfate", "Select Committee on GRAS Substances (SCOGS) Opinion: Ammonium sulfate", "Panera Bread › Menu & Nutrition › Nutrition Information Profile", "Official Subway Restaurants U.S. Products Ingredients Guide", "Feeding Ammonium Sulfate to Form Combined Chlorine Residual", Centers for Disease Control and Prevention, "Effects of Ammonium Phosphate and Sulfate on the Pyrolysis and Combustion of Cellulose", "PAKISTAN: 'Anti-terrorist' fertilizer ban hinders farmers", International Fertilizer Development Center, https://en.wikipedia.org/w/index.php?title=Ammonium_sulfate&oldid=953757447, Creative Commons Attribution-ShareAlike License, 235 to 280 °C (455 to 536 °F; 508 to 553 K) (decomposes), This page was last edited on 28 April 2020, at 22:38. At room temperature it crystallises in the orthorhombic system, with cell sizes of a = 7.729 Å, b = 10.560 Å, c = 5.951 Å. Volume 68: Ari L. Horvath and Forrest W. Getzen. It has a role as a fertilizer. Some early volumes have already been revised and updated to include new experimental measurements and to incorporate new approaches to critical evaluation. Lorimer and A. Maczynski. Dirkse. Starting with Volume 66 the series has been published by the Journal of Physical and Chemical Reference Data in cooperation with the US National Institute of Standards and Technology and is now formally known as the IUPAC-NIST Solubility Data Series. Volume 44: H. Miyamoto, E.M. Woolley and M. Salomon. Ammonium sulfate is also utilized in the purification ... fractionation on the basis of solubility in aqueous solutions of salts and organic solvents. Solubility is the property of a solid, liquid or gaseous chemical substance called solute to dissolve in a solid, liquid or gaseous solvent.The solubility of a substance fundamentally depends on the physical and chemical properties of the solute and solvent as well as on temperature, pressure and presence of other chemicals (including changes to the pH) of the solution.

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